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Statistical foundations of thermodynamics. I. Asymptotic form of the frequency functions

  • It is shown that, for all conceivable ensembles of statistical thermodynamics, at the thermodynamic limit, the frequency function of the fluctuations of macroscopic extensive parameters equals a Gaussian. The proof is based on a generalisation of Khinchin's method using the concept of "smoothed frequency functions."

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Metadaten
Author:E. Still, Karl Haubold, Arnold MünsterGND
URN:urn:nbn:de:hebis:30:3-740595
DOI:https://doi.org/10.1515/zna-1969-0204
ISSN:1865-7109
Parent Title (German):Zeitschrift für Naturforschung, A
Publisher:Verlag der Zeitschrift für Naturforschung
Place of publication:Tübingen
Document Type:Article
Language:English
Date of Publication (online):2014/06/02
Year of first Publication:1969
Publishing Institution:Universitätsbibliothek Johann Christian Senckenberg
Release Date:2024/02/08
Volume:24.1969
Issue:2
Page Number:5
First Page:201
Last Page:205
Institutes:Biochemie, Chemie und Pharmazie / Biochemie und Chemie
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Sammlungen:Universitätspublikationen
Licence (German):License LogoCreative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0