Zur Reaktivität von Isocyanaten mit Tris(dimethylamino)arsin
The Reactivity of Isocyanates with Tris(dimethylamino)arsine
- As[N(CH3)2]3 reacts with the following isocyanates: FSO2NCO, n-C4F9SO2NCO, SO2(NCO)2 and (CH3)3SiNCO. The products which result from reaction of FSO2NCO and n-C4F9SO2NCO are the acyclic tri- and bisubstituted arsines [xxx] In contrast, SO2(NCO)2 and (CH3)3SiNCO form eight- and four-membered ring compounds, where the skeleton consists of the atoms As2S2N4 (3) and As2N2 (4). The new compounds were characterized by NMR and mass spectra.
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| Author: | Herbert W. RoeskyORCiDGND, Georg Sidiropoulos |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-719005 |
| DOI: | https://doi.org/10.1515/znb-1977-0606 |
| ISSN: | 1865-7117 |
| ISSN: | 0932-0776 |
| Parent Title (German): | Zeitschrift für Naturforschung, B |
| Publisher: | Verlag der Zeitschrift für Naturforschung |
| Place of publication: | Tübingen |
| Document Type: | Article |
| Language: | German |
| Date of Publication (online): | 2014/06/02 |
| Year of first Publication: | 1977 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2024/01/09 |
| Tag: | Cyclic S-N-Compounds; Insertion Reactions; Isocyanates |
| Volume: | 32.1977 |
| Issue: | 6 |
| Page Number: | 3 |
| First Page: | 628 |
| Last Page: | 630 |
| Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |
