1,3,5,7-Tetra­kis(4-iodo­phen­yl)adamantane benzene tetra­solvate

  • The title mol­ecule, C34H28I4·4C6H6, has crystallographic 4 symmetry and crystallizes with four symmetry-related benzene solvent mol­ecules. The phenyl group is eclipsed with one of the adamantane C—C bonds. The tetra­phenyl­adamantane units and the benzene solvent mol­ecules are connected by weak inter­molecular phen­yl–benzene C—H⋯π and benzene–benzene C—H⋯π inter­actions. In the crystal, mol­ecules are linked along the c-axis direction via the iodo­phenyl groups by a combination of weak inter­molecular I⋯I [3.944 (1) Å] and I⋯π(phen­yl) [3.608 (6) and 3.692 (5) Å] inter­actions.

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Author:Jan W. Bats, Steffen Pospiech, Thomas F. PrisnerORCiD
Parent Title (German):Acta crystallographica. Section E, Structure reports online, 66.2010, S. o1636
Publisher:International Union of Crystallography
Place of publication:Chester
Document Type:Article
Date of Publication (online):2010/06/16
Date of first Publication:2010/06/16
Publishing Institution:Universitätsbibliothek Johann Christian Senckenberg
Release Date:2016/02/01
Page Number:8
This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence http://creativecommons.org/licenses/by/2.0/uk/legalcode , which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
Institutes:Biochemie, Chemie und Pharmazie / Biochemie und Chemie
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Licence (German):License LogoCreative Commons - Namensnennung 2.0