Selective one-pot syntheses of mixed silicon-germanium heteroadamantane clusters
- SixGey alloys are emerging materials for modern semiconductor technology. Well-defined model systems of the bulk structures aid in understanding their intrinsic characteristics. Three such model clusters have now been realized in the form of the SixGey heteroadamantanes [0], [1], and [2] through selective one-pot syntheses starting from Me2GeCl2, Si2Cl6, and [nBu4N]Cl. Compound [0] contains six GeMe2 and four SiSiCl3 vertices, whereas one and two of the GeMe2 groups are replaced by SiCl2 moieties in compounds [1] and [2], respectively. Chloride-ion-mediated rearrangement quantitatively converts [2] into [1] at room temperature and finally into [0] at 60 °C, which is not only remarkable in view of the rigidity of these cage structures but also sheds light on the assembly mechanism.
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| Author: | Benedikt Köstler, Michael BolteORCiD, Hans-Wolfram LernerORCiDGND, Matthias WagnerORCiD |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-644831 |
| DOI: | https://doi.org/10.1002/chem.202102732 |
| ISSN: | 1521-3765 |
| Parent Title (English): | Chemistry - a European journal |
| Publisher: | Wiley-VCH |
| Place of publication: | Weinheim |
| Document Type: | Article |
| Language: | English |
| Date of Publication (online): | 2021/08/13 |
| Date of first Publication: | 2021/08/13 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2021/11/16 |
| Tag: | SiGe alloys; cluster compounds; germanium; rearrangements; silicon |
| Volume: | 27 |
| Issue: | 58 |
| Page Number: | 4 |
| First Page: | 14401 |
| Last Page: | 14404 |
| Note: | The authors are grateful to Evonik Operations GmbH, Rheinfel- den (Germany), for the generous donation of Si2Cl6 and GeCl4. Open Access funding enabled and organized by Projekt DEAL. |
| HeBIS-PPN: | 48881460X |
| Institutes: | Biochemie, Chemie und Pharmazie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - Namensnennung-Nicht kommerziell - Keine Bearbeitung 4.0 |
