Mechanochemical synthesis of a cocrystal of two supramolecular hydrogen-bonded aggregates of 1,3,6,8-tetraazatricyclo[4.3.1.13,8]undecane (tatu) with 4-tert-butylphenol bearing different hydrogen bonding interactions
- The synthesis and single crystal structure of a new cocrystal, which is composed of OHphenolic∙∙∙OHphenolic∙∙∙Naminalic supramolecular heterosynthons assembled from 4-tert-butylphenol and the macrocyclic aminal TATU, is presented. This cocrystal was prepared by solvent-free assisted grinding, which is a commonly used mechanochemical method. Crystal structure, supramolecular assembly through hydrogen bonding interactions as well as the physical and spectroscopic properties of the title cocrystal are presented in this paper.
Author: | Augusto RiveraORCiD, Jicli José Rojas, Jaime Ríos-MottaORCiD, Michael BolteORCiD |
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URN: | urn:nbn:de:hebis:30:3-535725 |
DOI: | https://doi.org/10.3390/cryst8080309 |
ISSN: | 2073-4352 |
Parent Title (English): | Crystals |
Publisher: | MDPI |
Place of publication: | Basel |
Document Type: | Article |
Language: | English |
Date of Publication (online): | 2018/07/30 |
Date of first Publication: | 2018/07/30 |
Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
Release Date: | 2020/06/17 |
Tag: | aminal structure; cocrystals; crystal engineering; hydrogen bonds; noncovalent interactions; supramolecular chemistry |
Volume: | 8 |
Issue: | 8, Art. 309 |
Page Number: | 8 |
First Page: | 1 |
Last Page: | 8 |
Note: | This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited |
HeBIS-PPN: | 466838115 |
Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
Sammlungen: | Universitätspublikationen |
Licence (German): | Creative Commons - Namensnennung 4.0 |