rac-4-Chloro-2-[({2-[(3-chloro-6-hydroxy-2,4-dimethylbenzyl)(methyl)amino]propyl}(methyl)amino)methyl]-3,5-dimethylphenol
- The title compound, C23H32Cl2N2O2, a potential chiral ligand for coordination chemistry, was prepared by a two-step reaction. The molecule is located on a crystallographic centre of inversion. As a result, the methyl group bonded to the methylene group is disordered over two equally occupied positions, sharing the same site as the H atom of the chiral C atom. As a further consequence of the crystallographic centrosymmetry, the 1,2-diaminopropane unit adopts an antiperiplanar conformation and the two benzene rings are coplanar. The central chain is in an all-trans arrangement. An intramolecular O-H...N hydrogen bond makes an S(6) ring motif. A C-H...[pi] interaction links the molecules into one-dimensional chains along the [001] direction.
Author: | Augusto RiveraORCiD, Dency Jose Pacheco, Jaime Ríos-MottaORCiD, Mauricio Maldonado, Michael BolteORCiD |
---|---|
URN: | urn:nbn:de:hebis:30:3-274295 |
DOI: | https://doi.org/10.1107/S1600536812039694 |
ISSN: | 1600-5368 |
Parent Title (English): | Acta crystallographica / Section E, Structure reports online |
Publisher: | Munksgaard |
Place of publication: | Copenhagen |
Document Type: | Article |
Language: | English |
Year of Completion: | 2012 |
Year of first Publication: | 2012 |
Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
Release Date: | 2012/11/01 |
Volume: | 68 |
Issue: | o2997 |
Page Number: | 7 |
HeBIS-PPN: | 358450799 |
Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
Sammlungen: | Universitätspublikationen |
Licence (German): | Creative Commons - Namensnennung 2.0 |