Röntgenspektroskopische Untersuchung der chemischen Bindung in Oxiden
- This paper reports about the fine structure in the O—K-spectra of the oxides BeO, MgO, CaO, SrO, BaO, Sc2O5, Y2O3, La2O3, Sm2O3, Yb2O3, NiO and ZnO. The spectra show the satellite lines α3, α4, α5, α6 on the short wavelength side of the main line α1,2 and a shoulder β′ on its long wavelength side. The wavelengths of all lines depend on the nature of the oxide. For the positions of the lines Kα1.2 in the spectra no systematic relation to other data of the oxides is observed. On the other hand the distance of the a4-satellite from the α1,2-line decreases with increasing electronegativity of the metal atom in the oxide. This distance can be used as a measure for the ionic character of the metal-oxygen bond in these compounds.
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| Author: | Hans-Ulrich ChunGND, Dieter Hendel |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-742086 |
| DOI: | https://doi.org/10.1515/zna-1967-0919 |
| ISSN: | 1865-7109 |
| Parent Title (German): | Zeitschrift für Naturforschung, A |
| Publisher: | Verlag der Zeitschrift für Naturforschung |
| Place of publication: | Tübingen |
| Document Type: | Article |
| Language: | German |
| Date of Publication (online): | 2014/06/02 |
| Year of first Publication: | 1967 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2023/06/22 |
| Volume: | 22 |
| Issue: | 9 |
| Page Number: | 7 |
| First Page: | 1401 |
| Last Page: | 1407 |
| HeBIS-PPN: | 510577393 |
| Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |
