Crystal structure of 1,1'-[imidazolidine-1,3-diylbis(methyl­ene)]bis­­(naphthalen-2-ol)

  • The crystal structure of the title compound, C25H24N2O2, at 173 K has monoclinic (C2/c) symmetry. The mol­ecule is located on a crystallographic twofold rotation axis with only half a mol­ecule in the asymmetric unit. The imidazolidine ring adopts a twist conformation, with a twist about the ring C—C bond. The crystal structure shows the anti­clinal disposition of the two (2-hy­droxy­naphthalen-1-yl)methyl substituents of the imidazolidine ring. The structure displays two intra­molecular O—H⋯N hydrogen bonds, each forming an S(6) ring motif.

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Author:Augusto RiveraORCiD, Jicli José Rojas, Jaime Ríos-MottaORCiD, Michael BolteORCiD
Parent Title (German):Acta crystallographica. Section E, Crystallographic communications
Publisher:International Union of Crystallography
Place of publication:Chester
Document Type:Article
Date of Publication (online):2015/02/07
Date of first Publication:2015/02/07
Publishing Institution:Universitätsbibliothek Johann Christian Senckenberg
Release Date:2016/01/29
Tag:(2-hy­droxy­naphthalen-1-yl)meth­yl; crystal structure; hydrogen bonding; imadazolidine
Page Number:7
First Page:258
Last Page:260
This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence , which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
Institutes:Biochemie, Chemie und Pharmazie / Biochemie und Chemie
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Licence (German):License LogoCreative Commons - Namensnennung 2.0