Mechanochemical synthesis of a cocrystal of two supramolecular hydrogen-bonded aggregates of 1,3,6,8-tetraazatricyclo[,8]undecane (tatu) with 4-tert-butylphenol bearing different hydrogen bonding interactions

  • The synthesis and single crystal structure of a new cocrystal, which is composed of OHphenolic∙∙∙OHphenolic∙∙∙Naminalic supramolecular heterosynthons assembled from 4-tert-butylphenol and the macrocyclic aminal TATU, is presented. This cocrystal was prepared by solvent-free assisted grinding, which is a commonly used mechanochemical method. Crystal structure, supramolecular assembly through hydrogen bonding interactions as well as the physical and spectroscopic properties of the title cocrystal are presented in this paper.

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Author:Augusto RiveraORCiD, Jicli José Rojas, Jaime Ríos-MottaORCiD, Michael BolteORCiD
Parent Title (English):Crystals
Place of publication:Basel
Document Type:Article
Date of Publication (online):2018/07/30
Date of first Publication:2018/07/30
Publishing Institution:Universitätsbibliothek Johann Christian Senckenberg
Release Date:2020/06/17
Tag:aminal structure; cocrystals; crystal engineering; hydrogen bonds; noncovalent interactions; supramolecular chemistry
Issue:8, Art. 309
Page Number:8
First Page:1
Last Page:8
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited
Institutes:Biochemie, Chemie und Pharmazie / Biochemie und Chemie
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Licence (German):License LogoCreative Commons - Namensnennung 4.0